Talking about electronics, ambipolar transport describes only the motion of excess charge carrier concentrations, not equilibrium concentrations. Ambipolar transport has nothing to do with balanced charge carrier transport or mobilities!
Read the details here:
"On the use of the term “ambipolar"
[doi: 10.1063/1.3641898]
Read the details here:
"On the use of the term “ambipolar"
[doi: 10.1063/1.3641898]
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